Restricted Rotation in Aromatic Ketones. I. Substituent Effects on the Barrier to Rotation about the Benzene-to-Carbonyl Bond
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Solvent Effects on the Barrier to Rotation in Carbamates.
In the 40 years since the inception of dynamic NMR methods, much effort has been invested to quantify and understand the barrier to rotation about the C-N bond in amides.1 Carbamates, which also exhibit the approximately planar N-CdO framework responsible for hindered rotation in amides, have received considerably less attention, although they are important biologically as anticonvulsants, loca...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1972
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.45.2565